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Download PDF by B. Mistry: A Handbook of Spectroscopic Data Chemistry : UV, IR, PMR,

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Additional info for A Handbook of Spectroscopic Data Chemistry : UV, IR, PMR, CNMR and Mass Spectroscopy

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Etones ('=0 str. secondary' amide. 02 s. ex, P unsat. acyclic or 6 ring ketones ca. 1690 ca. 92 s. C=O str. Primary amides, amide I band C=O str. 99 W. 99 s. CR IR 2=CR 3R4 , a1kenes o-hydroxy (amino) C=C str. 1690-1670 benzoates C=O str. 92-6-04 s. 92-6-01 v. oximes, oxazines, oxazo1ines, C=O str. same ring oxazolones, azomethines, acyclic C=N C=N str. ca. 1680 ca. 95 s. Large-ring cyclic lactams C=O str. 02 s. Conj. polyene aldehydes C=O str. 95-6-06 s. Intramolecular H-bonded carboxylic acids C=O str.

7-3 12 s. 01 s. Si-F str. 0 Si-C def. Ca. 1260 Ca. 94 v. -so Si-C str. -s. sym. =symmetric s=strong absorption w=weak absorption def. 86 v. , sh. sh. Alcohols, phenols, free OH O-H str. Oximes (R-C = NOH) O-H str. R-OH, Ar-OH, intramolecular hydrogen bonded O-H str. 86 m. • sh. R-OH, Ar-OH, dimeric O-H str. 12 w. Ketones, C=O overtone C=O str. N-H str. , d. , d. 91 s. 11 m. 93 s. O-H str. free NH secondary amines N-H str. Sec. amides, free NH (trans) N-H str. Nitrites (R-O-N=O) overtones N=O str.

26 s, Acyclic C-O str. 51-9,57 s, Free OH O-H str. 82-286 m, Bonded OH O-H str. 00-4,00 w" br. fine structure bands2700-2500 3,70-4-00 w. v, b) Carboxylic acids AIIOH O-H def. 24 Solid fatty acids CH 2 vib. 48 w. characteristic pattern -COOH C-O str. plus O-H def. 17 w. 13 s, C-O str, 1200-1170 8 33-8,55 s, c) Esters Propionates and higher esters 30 Spectroscopic Data Chemistry Esters of aromatic C-O str. 00 s. C-O str. 33 s. Esters of a, 13 unsat. C-O str. 00 s. , d. 82 w. s. , asym. e) Ketones CH 3 -CO CH2 -CO- t) Arnides primary, free NH CH 3 def.

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